Au → M bonds promote catalytic alkyne hydrofunctionalisation.
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DOI: 10.1039/d3cc01008b
Abstract: The impact of metalloligands on Au catalysed alkyne hydrofunctionalisation is studied. Ambiphilic PMP-type ligands (M = CuI, AgI, ZnII) stabilise Au → M bonds including unprecedented AuI → ZnII interactions. The Lewis acidity of Au… read more here.
Keywords: alkyne hydrofunctionalisation; znii; promote catalytic; hydrofunctionalisation ... See more keywords