Plasma-Catalytic Ammonia Synthesis beyond the Equilibrium Limit
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c00684
Abstract: We explore the consequences of non-thermal plasma activation on product yields in catalytic ammonia synthesis, a reaction that is equilibrium-limited at elevated temperatures. We employ a minimal m... read more here.
Keywords: plasma catalytic; equilibrium; catalytic ammonia; ammonia synthesis ... See more keywords
Catalytic Ammonia Synthesis Mediated by Molybdenum Complexes with PN3P Pincer Ligands: Influence of P/N Substituents and Molecular Mechanism
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27227843
Abstract: Three molybdenum trihalogenido complexes supported by different PN3P pincer ligands were synthesized and investigated regarding their activity towards catalytic N2-to-NH3 conversion. The highest yields were obtained with the H-PN3PtBu ligand. The corresponding Mo(V)-nitrido complex also… read more here.
Keywords: catalytic ammonia; molybdenum; mechanism; pincer ligands ... See more keywords