Cobalt Pincer Complexes in Catalytic C-H Borylation: The Pincer Ligand Flips Rather Than Dearomatizes.
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DOI: 10.1021/acscatal.8b03146
Abstract: The mechanism for the borylation of an aromatic substrate by a cobalt pincer complex was investigated by density functional theory calculations. Experimental observations identified trans-(iPrPNP)CoH2(BPin) as the resting state in the borylation of five-membered heteroarenes,… read more here.
Keywords: pincer; borylation; cobalt pincer; catalytic borylation ... See more keywords