Mechanistic insights into catalytic carboxylic ester hydrogenation with cooperative Ru(II)-bis{1,2,3-triazolylidene}pyridine pincer complexes
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DOI: 10.1016/j.jorganchem.2017.01.003
Abstract: Transmetallation of newly designed lutidine-based CNC or CNN ligands L, featuring flanking 1,2,3-triazolylidene (tzNHCs) moieties, from Ag(I) to Ru(II) provided access to well-defined cationic [RuII(CO)(H)(L)(PPh3)]+ complexes 2 and 5. Spectroscopic investigations confirm that, in both… read more here.
Keywords: ester hydrogenation; ester; mechanistic insights; catalytic carboxylic ... See more keywords