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Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03646
Abstract: Four new complexes containing the bis(pentamethylcyclopentadienyl)thorium(IV) moiety, Cp*2Th(L1)(Me) (Th2), Cp*2Th(L2)(Me) (Th3), Cp*2Th(L1)Cl (Th5), and Cp*2Th(L2)Cl (Th6), were synthesized in quantitative yields via the protonolysis reaction of the metallocene precursor complexes Cp*2Th(Me)2 (Th1) and Cp*2Th(Me)Cl (Th4)…
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Keywords:
iminato ligand;
ligand catalytic;
sacrificial iminato;
catalytic cyanosilylation ... See more keywords
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Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt00043c
Abstract: The ability of a platinum compound to act as a catalyst for the cyanosilylation of carbonyl compounds is demonstrated through a well-defined germylene stabilized Pt(ii) dicyanide, trans-{(iBu)2ATIGe(iPr)}2Pt(CN)2.
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Keywords:
platinum;
catalytic cyanosilylation;
cyanosilylation using;
germylene stabilized ... See more keywords