Chemoselective Catalytic Dehydrogenative Cross-Coupling of 2-Acylimidazoles: Mechanistic Investigations and Synthetic Scope
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DOI: 10.1021/acscatal.8b02361
Abstract: Chemoselective iron-catalyzed dehydrogenative cross-coupling using 2-acylimidazoles is described. The addition of a phosphine oxide ligand substantially facilitated the generation of tert-butoxy radicals from di-tert-butyl peroxide, allowing for efficient benzylic C–H bond cleavage under mild conditions.… read more here.
Keywords: dehydrogenative cross; chemoselective catalytic; cross; coupling acylimidazoles ... See more keywords
Catalyst Development in the Dehydrogenative Borylation of Alkenes for the Synthesis Vinylboronate Esters
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DOI: 10.1055/s-0040-1707275
Abstract: Catalytic dehydrogenative borylation of alkenes provides an efficient and straightforward method for the preparation of synthetically useful vinylboronate esters. Here, we present a summary of developments and recent advances in this area, classified according to… read more here.
Keywords: catalytic dehydrogenative; borylation alkenes; dehydrogenative borylation; vinylboronate esters ... See more keywords