Neighbouring effects on catalytic epoxidation by Fe-cyclam in M2-PDIxCy complexes.
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DOI: 10.1039/d0dt03758c
Abstract: The unsymmetric PDIeCy ligand, featuring pyridinediimine and cylam sites, can be selectively metalated. Complementing the diiron compound, we have synthesized two heterobimetallic isomers, [ZnPDIFeCy(PDIeCy)(OTf)4] (3) and [FePDIZnCy(PDIeCy)(OTf)4] (4), and a dizinc complex, [Zn2(PDIeCy)(OTf)4] (5). Olefin… read more here.
Keywords: catalytic epoxidation; neighbouring effects; pdiecy otf; effects catalytic ... See more keywords
Catalytic epoxidation of β-ionone with molecular oxygen using selenium-doped silica materials
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DOI: 10.1039/d1nj03311e
Abstract: Se-doped silica could catalyze the β-ionone epoxidation reaction. Interestingly, by doping with fluorine in the catalyst, the reaction selectivity was significantly enhanced. The metal-free process is suitable for pharmaceutical synthesis. read more here.
Keywords: catalytic epoxidation; doped silica; ionone molecular; epoxidation ... See more keywords
Advances in Designing Au Nanoparticles for Catalytic Epoxidation of Propylene with H2 and O2
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DOI: 10.3390/catal10040442
Abstract: Au nanoparticles, which can be used in various industrial and environmental applications, have drawn substantial research interest. In this review, a comprehensive background and some insights are provided regarding recent studies concerning the use of… read more here.
Keywords: catalytic epoxidation; advances designing; epoxidation; nanoparticles catalytic ... See more keywords