Catalytic Generation of Remote C-N Axial Chirality through Atroposelective de novo Arene Construction.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03272
Abstract: The first atroposelective desymmetrization of prochiral N-aryl maleimides through its conversion to axially chiral phthalimides is developed by applying a de novo arene construction strategy. Catalyzed by bis(3,5-dimethylphenyl)prolinol TMS-ether, this reaction proceeds through oxidative [4… read more here.
Keywords: catalytic generation; novo arene; arene construction; generation remote ... See more keywords
Catalytic generation of alkoxy radicals from unfunctionalized alcohols
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc04542j
Abstract: This review summarizes recent advances in the catalytic generation of alkoxy radicals from unfunctionalized alcohols and highlights current methods for O–H bond activation. read more here.
Keywords: catalytic generation; generation alkoxy; alkoxy radicals; unfunctionalized alcohols ... See more keywords