Molecularly Defined Polyolefin Vitrimers from Catalytic Insertion Polymerization.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c03778
Abstract: Vitrimers can combine the advantageous properties of cross-linked materials with thermoplastic processability. For the prominent case of polyethylene, established post-polymerization introduction of cross-linkable moieties results in extremely heterogeneous compositions of the chains. Here, we report… read more here.
Keywords: cross; cross linkable; insertion polymerization; catalytic insertion ... See more keywords
Catalytic insertion of nitrenes into B–H bonds
Sign Up to like & getrecommendations! Published in 2025 at "Chemical Science"
DOI: 10.1039/d5sc00723b
Abstract: Organic compounds with boron–nitrogen bonds are widely used as fluorescent sensors and semiconducting materials. This paper presents a new approach for the formation of B–N bonds via catalytic insertion of nitrenes into B–H bonds. The… read more here.
Keywords: catalytic insertion; insertion nitrenes; nitrenes bonds;