Catalytic Lewis Base Additive Enables Selective Copper-Catalyzed Borylative α-C–H Allylation of Alicyclic Amines
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DOI: 10.1021/jacs.2c07969
Abstract: Functionalized alicyclic amines are important building blocks for the synthesis of bioactive natural compounds and drugs. Existing methods of functionalization are typically limited to the synthesis of protected amines or the use of highly basic… read more here.
Keywords: lewis base; base additive; copper catalyzed; catalytic lewis ... See more keywords
Catalytic Lewis and Brønsted acid syn-diastereoselective benzylic substitutions of α-hydroxy-β-nitro- and α-hydroxy-β-azido-alkyl arenes
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DOI: 10.1139/cjc-2020-0016
Abstract: A series of alkyl and alkenyl p-methoxy arenes containing α,β-disubstituted diamino and amino alcohol groups were synthesized from β-nitro and β-azido benzylic alcohols in the presence of AuCl3 as ... read more here.
Keywords: alkyl; catalytic lewis; nsted acid; lewis nsted ... See more keywords