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   Articles with "catalytic metal" as a keyword



Co‐Catalytic Metal‐Support Interactions Design on Single‐Atom Alloy for Boosted Electro‐Reduction of Nitrate to Nitrogen

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recommendations! Published in 2024 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202406917

Abstract: The past decades have seen considerable imbalances in the nitrogen cycle due to the excessive use of nitrate in agriculture and industry. Electrocatalytic reduction of nitrate (NO3RR) to nitrogen (N2) holds significant potential for addressing… read more here.

Keywords: catalytic metal; nitrogen; reduction nitrate; reduction ... See more keywords

Practical synthesis of active O-2-(2-propylsulfinyl)benzyl (OPSB) glycosides via a catalytic and metal free oxidation of latent O-2-(2-propylthiol)benzyl (OPTB) glycosides.

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recommendations! Published in 2018 at "Carbohydrate research"

DOI: 10.1016/j.carres.2018.08.014

Abstract: A catalytic and metal free sulfoxidation of O-2-(2-propylthiol)benzyl (OPTB) glycosides to O-2-(2-propylsulfinyl)benzyl (OPSB) glycosides has been developed by introducing NOBF4 as catalyst, oxygen as terminal oxidant and TBAB as additive. Wide variety of OPTB glycosides… read more here.

Keywords: benzyl; optb glycosides; catalytic metal; metal free ... See more keywords

Catalytic and metal-free intramolecular hydroalkoxylation of alkynes

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recommendations! Published in 2019 at "Tetrahedron Letters"

DOI: 10.1016/j.tetlet.2019.01.020

Abstract: Abstract Benzyltrimethylammonium hydroxide act as an efficient metal-free catalyst for the intramolecular hydroalkoxylation of alkynes. Notably, the use of microwave irradiation allowed reaction to operate in only two minutes. Under optimized reaction conditions, linear alkynes… read more here.

Keywords: catalytic metal; intramolecular hydroalkoxylation; hydroalkoxylation alkynes; metal free ... See more keywords

Cooperative Strategies for Catalytic Hydrogenation of Unsaturated Hydrocarbons

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recommendations! Published in 2017 at "ACS Catalysis"

DOI: 10.1021/acscatal.7b02203

Abstract: This Perspective discusses catalytic hydrogenation reactions of alkenes, alkynes, and other unsaturated C-C substrates in which the catalyst design involves cooperative strategies that enable bifunctional H2 activation and delivery. These approaches complement the more traditional… read more here.

Keywords: hydrogenation; catalytic metal; cooperative strategies; strategies catalytic ... See more keywords

Catalytic Metal Ion–Substrate Coordination during Nonenzymatic RNA Primer Extension

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recommendations! Published in 2024 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.4c00323

Abstract: Nonenzymatic template-directed RNA copying requires catalysis by divalent metal ions. The primer extension reaction involves the attack of the primer 3′-hydroxyl on the adjacent phosphate of a 5′-5′-imidazolium-bridged dinucleotide substrate. However, the nature of the… read more here.

Keywords: primer extension; catalytic metal; metal; ion ... See more keywords