Utilization of CO2 as a C1 Building Block for Catalytic Methylation Reactions
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DOI: 10.1021/acscatal.6b02715
Abstract: Developing new synthetic approaches for benign CO2 utilization is of current interest. In this respect, reductive alkylations using N- or C-based nucleophiles to give the corresponding methyl amines and (hetero)arenes are investigated intensively. Crucial points… read more here.
Keywords: utilization co2; block catalytic; building block; catalytic methylation ... See more keywords
Tandem catalytic methylation of naphthalene using CO2 and H2.
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DOI: 10.1039/d2cc00190j
Abstract: We report here the direct methylation of naphthalene using CO2 and H2, which is distinctly more effective than the counterpart methylation with methanol. Benefiting from well-balanced specific rates for CO2-to-methanol conversion over ZnZrOx and the… read more here.
Keywords: methylation; tandem catalytic; methylation naphthalene; using co2 ... See more keywords
Bicyclic (alkyl)(amino)carbene (BICAAC) in a dual role: activation of primary amides and CO2 towards catalytic N-methylation
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DOI: 10.1039/d3sc01216f
Abstract: Herein, we report the first catalytic methylation of primary amides using CO2 as a C1 source. A bicyclic (alkyl)(amino)carbene (BICAAC) exhibits dual role by activating both primary amide and CO2 to carry out this catalytic… read more here.
Keywords: alkyl amino; amino carbene; carbene bicaac; primary amides ... See more keywords