Mechanism and Application of the Catalytic Reaction of [NiFe] Hydrogenase: Recent Developments
Sign Up to like & getrecommendations! Published in 2020 at "ChemBioChem"
DOI: 10.1002/cbic.202000058
Abstract: Hydrogenases (H2ase) catalyze the oxidation of dihydrogen and the reduction of protons with remarkable efficiency, thereby attracting considerable attention in the energy field due to their biotechnological potential. For this simple reaction, [NiFe] H2ase has… read more here.
Keywords: nife h2ases; mechanism; catalytic reaction; reaction nife ... See more keywords
Catalytic reaction of ammonium perchlorate with energetic cobalt complex of 2,6-diamino-3,5-dinitropyrazine-1-oxide during thermal decomposition process
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Thermal Analysis and Calorimetry"
DOI: 10.1007/s10973-017-6263-y
Abstract: The purpose of this work was to study the catalytic reaction and its mechanism of ammonium perchlorate (AP) with cobalt complex of 2,6-diamino-3,5-dinitropyrazine-1-oxide (Co-LLM-105) during thermal decomposition process. At first, the catalytic performance of Co-LLM-105… read more here.
Keywords: ammonium perchlorate; catalytic reaction; llm 105; process ... See more keywords
Highly accurate and inexpensive procedures for computing chronoamperometric currents for the catalytic EC' reaction mechanism at an inlaid disk electrode
Sign Up to like & getrecommendations! Published in 2019 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2018.12.113
Abstract: Abstract In the former studies [L. K. Bieniasz, Electrochim. Acta 199 (2016) 1–11, 259 (2018) 1068–1080] a rigorous theory of chronoamperometry was elaborated, together with efficient and highly accurate computational procedures, for a single charge… read more here.
Keywords: inlaid disk; reaction; highly accurate; catalytic reaction ... See more keywords
Mechanism studies of hydrazine electro-oxidation by a platinum ultramicroelectrode: Effects of supporting electrolytes
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Electroanalytical Chemistry"
DOI: 10.1016/j.jelechem.2018.04.012
Abstract: Abstract The effects of the supporting electrolyte on electro-catalytic reaction of hydrazine hydrate (HH) were studied by a platinum ultramicroelectrode. We found that the H+ electric field generated during the catalytic process can partly hinder… read more here.
Keywords: catalytic reaction; value; steady state; reaction ... See more keywords
Photo-catalytic degradation of mixed gaseous HCHO and C6H6 in paper mills: Experimental and theoretical study on the adsorption behavior simulation and catalytic reaction mechanism.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of hazardous materials"
DOI: 10.1016/j.jhazmat.2019.121779
Abstract: VOCs in paper mills have severely exceeded the emission standards and their photo-catalytic degradations should focus on the experimental and theoretical studies. This work used TiO2 colloid as catalyst to study the photo-catalytic degradations of… read more here.
Keywords: degradation; adsorption; c6h6; catalytic reaction ... See more keywords
Automated Generation and Analysis of the Complex Catalytic Reaction Network of Ethanol Synthesis from Syngas on Rh(111)
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c00630
Abstract: Reactions on the surface of catalysts are rather complex, and many possible reaction pathways and intermediates are involved. We here propose a method that is able to automatically generate a catalytic reaction network and identify… read more here.
Keywords: automated generation; generation analysis; catalytic reaction; reaction network ... See more keywords
The Catalytic Reaction Mechanism of the β-Galactocerebrosidase Enzyme Deficient in Krabbe Disease
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DOI: 10.1021/acscatal.0c02609
Abstract: Krabbe disease is a neurodegenerative disorder related to misfunction of β-galactocerebrosidase (GALC), a glycosidase that cata-lyzes the cleavage of β-galactosidic bonds in glycosphingolipids. Her... read more here.
Keywords: krabbe; galactocerebrosidase; catalytic reaction; krabbe disease ... See more keywords
Discovering Catalytic Reaction Networks Using Deep Reinforcement Learning from First-Principles.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c08794
Abstract: Determining the reaction pathways, which is central to illustrating the working mechanisms of a catalyst, is severely hindered by the high complexity of the reaction and the extreme scarcity of the data. Here, we develop… read more here.
Keywords: framework; reaction networks; catalytic reaction; reinforcement learning ... See more keywords
Proving Cooperativity of a Catalytic Reaction by Means of Nanoscale Geometry: The Case of Click Reaction.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02556
Abstract: Establishing whether a reaction is catalyzed by a single-metal catalytic center or cooperatively by a fleeting complex encompassing two such centers may be an arduous pursuit requiring detailed kinetic, isotopic, and other types of studies─as… read more here.
Keywords: catalytic reaction; click reaction; reaction; geometry ... See more keywords
Ultra-thin Au tip structure: a novel SERS substrate for in situ observation of a p-aminothiophenol surface-catalytic reaction
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c6ra27799c
Abstract: A novel surface-enhanced Raman scattering (SERS) substrate based on an ultra-thin Au nano-tip structure was prepared using a simple and quick electrochemical etching method in this study. After decorating Au nanoparticles on the surface of… read more here.
Keywords: tip structure; surface; catalytic reaction; surface catalytic ... See more keywords
A catalytic reaction-based colorimetric assay of alkaline phosphatase activity based on oxidase-like MnO2 microspheres
Sign Up to like & getrecommendations! Published in 2019 at "Analytical Methods"
DOI: 10.1039/c9ay01772k
Abstract: A catalytic reaction-based colorimetric assay of alkaline phosphatase activity is developed based on oxidase-like MnO2 microspheres. read more here.
Keywords: assay alkaline; based colorimetric; catalytic reaction; colorimetric assay ... See more keywords