Solid‐Solution Coordination Polymers as Precursors for ZnxCd1–xS/C Composite Nanowires
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700289
Abstract: The development of synthetic routes to nanomaterials has been motivated by their potential applications in electronics, optics, and catalytic reactions. Solution-based synthesis has relied on organic stabilizers to regulate the crystal growth. Despite the beneficial… read more here.
Keywords: organic stabilizers; coordination polymers; solution; catalytic reactions ... See more keywords
Recent Advances in Functional Nanomaterials for Catalytic Generation of Nitric Oxide: A Mini Review.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202207261
Abstract: As a gaseous second messenger, nitric oxide (NO) plays an important role in a series of signal pathways. Research on the NO regulation for various disease treatments has aroused wide concern. However, the lack of… read more here.
Keywords: nitric oxide; functional nanomaterials; generation; advances functional ... See more keywords
Axis-Unfixed Biphenylphosphine-Oxazoline Ligands: Design and Applications in Asymmetric Catalytic Reactions.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical record"
DOI: 10.1002/tcr.202300133
Abstract: The design and synthesis of chiral ligands plays an important role in asymmetric catalytic reactions. Over the past decades, various types of chiral phosphine-oxazolines (PHOX ligands) have been developed and have greatly advanced the field… read more here.
Keywords: biphenylphosphine oxazoline; asymmetric catalytic; axis unfixed; unfixed biphenylphosphine ... See more keywords
Kinetics of cluster shape sensitive heterogeneous catalytic reactions
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.130642
Abstract: Abstract The theoretical framework for analysis of heterogeneous catalytic reactions on metals clusters sensitive to the cluster shape has been developed. Cubooctahedrons, cubes and semi-spherical particles have been considered having a different number of edge,… read more here.
Keywords: shape; shape sensitive; kinetics cluster; cluster shape ... See more keywords
Catalytic reactions on magnesium dichloride clusters saturated by titanium tetrachloride
Sign Up to like & getrecommendations! Published in 2020 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2020.111314
Abstract: Abstract Magnesium dichloride, titanium tetrachloride, and triethyl aluminum are essential components in the Ziegler-Natta catalysts for olefin polymerization. We report a systematic computational investigation (M06-2X/def-TZVP level of theory, thus accounting for dispersion) of the thermodynamics… read more here.
Keywords: titanium tetrachloride; dichloride clusters; catalytic reactions; magnesium dichloride ... See more keywords
Thermal Hysteresis Involving Reversible Self-Catalytic Reactions.
Sign Up to like & getrecommendations! Published in 2021 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.1c00090
Abstract: ConspectusHysteresis is ubiquitous in nature and biology. It appears in ferromagnetism, ferroelectrism, traffic congestion, river sedimentation, electronics, thermoresponses, cell division, differentiation, and apoptosis. Hysteresis phenomena are beyond equilibrium and involve nonlinear, bistable, time delay, and… read more here.
Keywords: thermal hysteresis; hysteresis; self catalytic; reversible self ... See more keywords
In Situ Reactor-Integrated Electrospray Ionization Mass Spectrometry for Heterogeneous Catalytic Reactions and Its Application in the Process Analysis of High-Pressure Liquid-Phase Lignin Depolymerization.
Sign Up to like & getrecommendations! Published in 2021 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.1c02710
Abstract: Process analysis of heterogeneous catalytic reactions such as lignin depolymerization is essential to understand the reaction mechanism at the molecular level, but it is always challenging due to harsh conditions. Herein, we report an operando… read more here.
Keywords: process analysis; catalytic reactions; depolymerization; heterogeneous catalytic ... See more keywords
OpenMKM: An Open-Source C++ Multiscale Modeling Simulator for Homogeneous and Heterogeneous Catalytic Reactions.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of chemical information and modeling"
DOI: 10.1021/acs.jcim.3c00088
Abstract: Microkinetic modeling is invaluable for coupling "microscale" atomistic data with "macroscale" reactor observables. We introduce an Open-source Microkinetic Modeling (OpenMKM) multiscale mean-field microkinetics modeling toolkit targeting mainly heterogeneous catalytic reactions but applies equally to homogeneous… read more here.
Keywords: software; reaction; source; heterogeneous catalytic ... See more keywords
Secondary Effectiveness Factors and Solubility Effects for Catalytic Reactions in Series
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c00185
Abstract: Thiele moduli and effectiveness factors are powerful ways to account for mass transfer limitations on reactions occurring within porous catalyst particles. Effectiveness factors have been developed... read more here.
Keywords: factors solubility; solubility effects; effects catalytic; secondary effectiveness ... See more keywords
Chemical Systems Involving Two Competitive Self-Catalytic Reactions
Sign Up to like & getrecommendations! Published in 2019 at "ACS Omega"
DOI: 10.1021/acsomega.9b00133
Abstract: Self-catalytic reactions are chemical phenomena, in which a product catalyzes the reactions of substrates further to yield products. A significant amplification of product concentration occurs during the reactions in a dilute solution, which exhibit notable… read more here.
Keywords: systems involving; involving two; self catalytic; chemical systems ... See more keywords
Deformable metal-organic framework nanosheets for heterogeneous catalytic reactions.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c02272
Abstract: The dynamic status near the surface of a catalyst can significantly affect the catalytic process, because the overall reaction rate depends on the mass velocity of product attachment and reactant detachment. As a dominant diffusion… read more here.
Keywords: heterogeneous catalytic; catalytic reactions; metal organic; organic framework ... See more keywords