Intrinsic defects promote rapid conversion of polysulfides on carbon surface to achieve high rate performance
Sign Up to like & getrecommendations! Published in 2021 at "Carbon"
DOI: 10.1016/j.carbon.2021.07.071
Abstract: Abstract Polysulfides can be captured rapidly by defects, which possess strong catalytic redox abilities. Species of defects have important influence on rate performance of metal-sulfur electrodes. However, catalytic reaction mechanisms have not been explored in… read more here.
Keywords: high rate; rate performance; catalytic redox; rate ... See more keywords
Catalytic and redox activity of nucleic acids at mercury electrodes: Roles of nucleobase residues
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Electroanalytical Chemistry"
DOI: 10.1016/j.jelechem.2019.113812
Abstract: Abstract Using a series of specifically designed oligonucleotides we have identified adenine and cytosine nucleobases as residues involved in catalytic hydrogen evolution reaction (CHER) of nucleic acids at the hanging mercury drop electrode (HMDE). Due… read more here.
Keywords: nucleic acids; activity nucleic; catalytic redox; redox activity ... See more keywords
Catalytic Redox Chain Ring Opening of Lactones with Quinones To Synthesize Quinone-Containing Carboxylic Acids.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b01672
Abstract: Catalytic ring opening of five- to eight-membered lactones with quinones is achieved through a redox chain mechanism. With low loading of a simple metal triflate Lewis acid catalyst and a chain initiator, C-H bonds of… read more here.
Keywords: chain; ring opening; redox chain; lactones quinones ... See more keywords