Mechanistic Insight into the Catalytic Staudinger Ligation.
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DOI: 10.1021/acs.orglett.8b04035
Abstract: Organophosphorus-catalyzed Staudinger ligation between carboxylic acids and azides in the presence of phenylsilane reductant produces amides. NMR-based mechanistic investigations revealed that the catalytic Staudinger ligation does not proceed via reduction of phosphine oxide but rather… read more here.
Keywords: catalytic staudinger; mechanistic insight; insight catalytic; ligation ... See more keywords