Articles with "catalytic systems" as a keyword



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Heterogeneous Catalytic Systems for Carbon Dioxide Hydrogenation to Value-Added Chemicals.

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Published in 2023 at "ChemPlusChem"

DOI: 10.1002/cplu.202300157

Abstract: Utilizing renewable energy to hydrogenate carbon dioxide into fuels eliminates massive CO2 emissions from the atmosphere and diminishes our need for using fossil fuels. This review presents the most recent developments for designing heterogeneous catalysts… read more here.

Keywords: carbon; systems carbon; hydrogenation; catalytic systems ... See more keywords
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Influence of a diimine ligand and an activator on the processes taking place in Brookhart-type nickel catalytic systems

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Published in 2017 at "Research on Chemical Intermediates"

DOI: 10.1007/s11164-017-3207-x

Abstract: Brookhart-type catalytic systems based on zero-valent nickel complexes Ni(COD)2 and Ni(COD)L [where COD is cyclooctadiene and L is bis-2,6-diisopropylphenyl-diazabutadiene (DPP-DAB) or N,N′-bis-2,6- diisopropylphenyl-bis-iminoacenaphthene (DPP-BIAN)] activated with Lewis acids such as methylaluminoxane (MAO) and boron trifluoride… read more here.

Keywords: brookhart type; diimine ligand; catalytic systems;
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Recent progress in preparation of branched polyethylene with nickel, titanium, vanadium and chromium catalytic systems and EPR study of related catalytic systems

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Published in 2019 at "European Polymer Journal"

DOI: 10.1016/j.eurpolymj.2019.109339

Abstract: Abstract Catalysts play a pivotal role in the olefin polymerization process. After decades of development, a growing number of transition metal catalysts have been widely used in the field of olefin polymerization. Among them, the… read more here.

Keywords: vanadium chromium; titanium vanadium; nickel titanium; catalytic systems ... See more keywords
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Efficient synthesis of bio-based activated carbon (AC) for catalytic systems: A green and sustainable approach

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Published in 2021 at "Journal of Industrial and Engineering Chemistry"

DOI: 10.1016/j.jiec.2021.01.044

Abstract: Abstract Tremendous efforts in developing sustainable processes for integrated production of value-added products/chemicals and fuels in biorefineries increase through delicate designs towards sustainability. This review focuses on the synthesis of activated carbon (AC) from renewable… read more here.

Keywords: activated carbon; catalytic systems; synthesis; sustainable approach ... See more keywords
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Recent progress in the development of catalytic systems for homogenous asymmetric hydrosilylation of ketones

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Published in 2020 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2020.121415

Abstract: Abstract Catalytic hydrosilylation of various multiple bonds provides access to numerous organosilicon compounds. One of the most important applications of this reaction is asymmetric hydrosilylation of prochiral ketones to give silyl ethers, which can be… read more here.

Keywords: progress; chemistry; catalytic systems; asymmetric hydrosilylation ... See more keywords
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The effect of ionic liquid containing AlCl3 catalytic systems on the microstructure and properties of polyalphaolefin based lubricants

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Published in 2021 at "Journal of Molecular Liquids"

DOI: 10.1016/j.molliq.2021.116299

Abstract: Abstract A new class of ionic liquid (IL) containing AlCl3 catalysts was synthesized from 1-methylimidazole, and different alkyl chlorides, including: 1-butyl chloride, cyclohexyl chloride and benzyl chloride, named as IL-But/AlCl3, IL-CH/AlCl3 and IL-Benz/AlCl3, respectively. The… read more here.

Keywords: liquid containing; catalytic systems; containing alcl3; ionic liquid ... See more keywords
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Recyclable supported Pd-NHC catalytic systems for the copper-free Sonogashira cross-coupling in flow

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Published in 2018 at "Sustainable Chemistry and Pharmacy"

DOI: 10.1016/j.scp.2018.06.003

Abstract: Abstract A new family of well-defined NHC-Pd complexes immobilised onto silica, alumina and titania is reported. The catalysts display activity and recyclability in the Sonogashira cross-coupling reactions under batch and continuous flow conditions. Under batch… read more here.

Keywords: catalytic systems; recyclable supported; sonogashira cross; cross coupling ... See more keywords
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Identifying Spatial Relationships in Metal-nanoparticle/Insulating-aerogel Catalytic Systems with Electron Tomography: Manual Segmentation vs. Machine-learning Classifiers

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Published in 2020 at "Microscopy and Microanalysis"

DOI: 10.1017/s1431927620019595

Abstract: Catalytic systems based on the incorporation of metal nanoparticles into insulating aerogels show great promise in optimizing multiple chemical reactions, including CO oxidation [1], contaminant remediation [2], and water splitting [3]. The method of incorporation… read more here.

Keywords: identifying spatial; metal; catalytic systems; spatial relationships ... See more keywords
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Dynamic Behavior of Metal Nanoparticles in Pd/C and Pt/C Catalytic Systems under Microwave and Conventional Heating.

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Published in 2017 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.7b09173

Abstract: Metal on carbon catalysts (M/C) are ubiquitously used in modern research and industry to carry out a variety of chemical transformations. Stable metal-support frameworks and inertness of the carbon materials are usually taken for granted… read more here.

Keywords: carbon; catalytic systems; metal; heating ... See more keywords
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Bioinspired construction of multi-enzyme catalytic systems.

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Published in 2018 at "Chemical Society reviews"

DOI: 10.1039/c7cs00914c

Abstract: Enzyme catalysis, as a green, efficient process, displays exceptional functionality, adaptivity and sustainability. Multi-enzyme catalysis, which can accomplish the tandem synthesis of valuable materials/chemicals from renewable feedstocks, establishes a bridge between single-enzyme catalysis and whole-cell… read more here.

Keywords: multi; multi enzyme; catalytic systems; enzyme catalysis ... See more keywords
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Controlled synthesis of Bi- and tri-nuclear Cu-oxo nanoclusters on metal–organic frameworks and the structure–reactivity correlations

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Published in 2021 at "Chemical Science"

DOI: 10.1039/d1sc05495c

Abstract: Precisely tuning the nuclearity of supported metal nanoclusters is pivotal for designing more superior catalytic systems, but it remains practically challenging. By utilising the chemical and molecular specificity of UiO-66-NH2 (a Zr-based metal–organic framework), we… read more here.

Keywords: catalytic systems; oxo nanoclusters; controlled synthesis; structure ... See more keywords