Self-supporting transition metal chalcogenides on metal substrates for catalytic water splitting
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.129645
Abstract: Abstract Transition metal chalcogenides (TMCs) are the fascinating replacement of noble catalysts in catalytic water splitting due to their unique physical and chemical properties and low cost. However, their industrial application is substantially restricted by… read more here.
Keywords: metal; metal substrates; self supporting; water splitting ... See more keywords
Theoretical Investigation of Catalytic Water Splitting by the Arene-Anchored Actinide Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01379
Abstract: Actinide complexes, which could enable the electrocatalytic H2O reduction, are not well documented because of the fact that actinide-containing catalysts are precluded by extremely stable actinyl species. Herein, by using relativistic density functional theory calculations,… read more here.
Keywords: arene anchored; investigation catalytic; arene; theoretical investigation ... See more keywords
Bioinspired Active Site with a Coordination-Adaptive Organosulfonate Ligand for Catalytic Water Oxidation at Neutral pH
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c03415
Abstract: Many enzymes use adaptive frameworks to preorganize substrates, accommodate various structural and electronic demands of intermediates, and accelerate related catalysis. Inspired by biological systems, a Ru-based molecular water oxidation catalyst containing a configurationally labile ligand… read more here.
Keywords: water oxidation; coordination; water; ligand ... See more keywords
Kinetics and mechanisms of catalytic water oxidation.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c8dt04341h
Abstract: The kinetics and mechanisms of thermal and photochemical oxidation of water with homogeneous and heterogeneous catalysts, including conversion from homogeneous to heterogeneous catalysts in the course of water oxidation, are discussed in this review article.… read more here.
Keywords: mechanisms catalytic; kinetics mechanisms; oxidation; water ... See more keywords
Surface-Active Ionic Liquids in Catalytic Water Splitting
Sign Up to like & getrecommendations! Published in 2019 at "Australian Journal of Chemistry"
DOI: 10.1071/ch18104
Abstract: We report the application of surface-active ionic liquids as ligands and optional reaction media in iridium-catalyzed water oxidations. Three novel catalysts with N,N-dialkylimidazolidin-2-ylidene ligands based on amphiphilic imidazolium ionic liquids were synthesized and characterized. Excellent… read more here.
Keywords: active ionic; ionic liquids; surface active; catalytic water ... See more keywords