In Situ Generation of Catalytically Relevant Nanoparticles from a Molecular Pincer Iridium Precatalyst during Polyol Deoxygenation
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c03180
Abstract: Pincer complexes such as (RPOCOP)Ir-based species (RPOCOP = κ3-C6H3-1,3-[OP(R)2]2) are widely used as precatalysts for organic transformations with many mechanistic studies of these transformations... read more here.
Keywords: pincer; catalytically relevant; generation catalytically; situ generation ... See more keywords
Catalytically Relevant Intermediates in the Ni-Catalyzed C(sp2)-H and C(sp3)-H Functionalization of Aminoquinoline Substrates.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b09109
Abstract: This Article describes the synthesis and characterization of cyclometalated aminoquinoline NiII σ-aryl and σ-alkyl complexes that have been proposed as key intermediates in Ni-catalyzed C-H functionalization reactions. These NiII complexes serve as competent catalysts for… read more here.
Keywords: catalytically relevant; niiii species; functionalization aminoquinoline; intermediates catalyzed ... See more keywords
Insights Into the Bifunctional Aphidicolan-16-ß-ol Synthase Through Rapid Biomolecular Modeling Approaches
Sign Up to like & getrecommendations! Published in 2018 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2018.00101
Abstract: Diterpene synthases catalyze complex, multi-step C-C coupling reactions thereby converting the universal, aliphatic precursor geranylgeranyl diphosphate into diverse olefinic macrocylces that form the basis for the structural diversity of the diterpene natural product family. Since… read more here.
Keywords: catalytically relevant; amino acids; cyclization; biomolecular modeling ... See more keywords