Single-Atom Fe-Catalyzed Acceptorless Dehydrogenative Coupling to Quinolines.
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DOI: 10.1021/jacs.4c06145
Abstract: A single-atom iron catalyst was found to exhibit exceptional reactivity in acceptorless dehydrogenative coupling for quinoline synthesis, outperforming known homogeneous and nanocatalyst systems. Detailed characterizations, including aberration-corrected HAADF-STEM, XANES, and EXAFS, jointly confirmed the presence… read more here.
Keywords: acceptorless dehydrogenative; atom catalyzed; catalyzed acceptorless; single atom ... See more keywords
Cobalt-catalyzed acceptorless dehydrogenative coupling of aminoalcohols with alcohols: direct access to pyrrole, pyridine and pyrazine derivatives.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc07427a
Abstract: Here, the first example is reported of a new, molecularly defined SNS-cobalt(ii) catalyst for the acceptorless dehydrogenative coupling (ADC) of unprotected amino alcohols with secondary alcohols leading to pyrrole and pyridine derivatives. read more here.
Keywords: catalyzed acceptorless; cobalt catalyzed; pyrrole pyridine; acceptorless dehydrogenative ... See more keywords
A general and efficient Mn-catalyzed acceptorless dehydrogenative coupling of alcohols with hydroxides into carboxylates
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DOI: 10.1039/c8qo00023a
Abstract: The direct oxidation of alcohols into carboxylic acids is an essential reaction for the synthesis of bulky and fine chemicals. Most current processes require the use of either strong and toxic oxidants or the presence… read more here.
Keywords: catalyzed acceptorless; general efficient; acceptorless dehydrogenative; dehydrogenative coupling ... See more keywords
Formation of Ylidenehydrazines Enabled by Manganese-Catalyzed Acceptorless Dehydrogenative Coupling
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DOI: 10.1039/d3qo01890c
Abstract: Catalytic dehydrogenation, which exhibits highly atom-economical and chemo selective properties, converts multiple green sustainable alcohols to critical molecules and is a highly desirable and elusive process; furthermore, the dehydrogenation of... read more here.
Keywords: formation ylidenehydrazines; enabled manganese; acceptorless dehydrogenative; catalyzed acceptorless ... See more keywords