Palladium(II) acetate catalyzed acylative cleavage of cyclic and acyclic ethers under neat conditions
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2017.10.080
Abstract: Abstract During the development of a palladium catalyzed C–H activation cross-coupling reaction involving acyl halides, it was noted that palladium(II) acetate catalyzes the acylative cleavage of tetrahydrofuran (used as a solvent) at room temperature to… read more here.
Keywords: acyclic ethers; acetate catalyzed; acylative cleavage; catalyzed acylative ... See more keywords
Isothiourea-Catalyzed Acylative Desymmetrization of Silicon-Centered Bisphenols.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c00946
Abstract: The preparation of optically pure organosilicon compounds bearing a stereogenic center at the silicon atom is an attractive but challenging enterprise. Herein we disclose an isothiourea (ITU)-catalyzed monoacylation reaction of silicon-centered bisphenols with 2,2-diphenylacetic pivalic… read more here.
Keywords: catalyzed acylative; isothiourea catalyzed; silicon centered; desymmetrization ... See more keywords