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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00103
Abstract: An iridium(III)-catalyzed regioselective acylmethylation of the cage B(4)-H bond in o-carborane acids with sulfoxonium ylides is demonstrated through B(4)-H activation in ethanol under very mild conditions, affording a number of B(4)-acylmethylated o-carboranes. Additionally, the selective…
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Keywords:
iridium iii;
catalyzed acylmethylation;
sulfoxonium ylides;
acylmethylation ... See more keywords