Highly Enantioselective Rhodium(I)-Catalyzed Alder-ene-type Cycloisomerization of 1,7-Enynes.
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DOI: 10.1021/acs.orglett.1c04171
Abstract: The transition-metal-catalyzed asymmetric cycloisomerization of 1,7-enynes is regarded as a formidable challenge due to the poor ability of 1,7-enynes to serve as bidentate ligands to metal. In this Letter, a highly enantioselective rhodium(I)-catalyzed Alder-ene-type cycloisomerization… read more here.
Keywords: cycloisomerization enynes; enantioselective rhodium; catalyzed alder; cycloisomerization ... See more keywords