Recent Developments in Pd(0)-Catalyzed Alkene Carboheterofunctionalization Reactions.
Sign Up to like & getrecommendations! Published in 2017 at "Asian journal of organic chemistry"
DOI: 10.1002/ajoc.201600577
Abstract: This review summarizes recent developments in palladium-catalyzed alkene carboalkoxylation and carboamination reactions. New synthetic methods that have been reported in the past four years are described, along with mechanistic issues and the influence of mechanism… read more here.
Keywords: alkene carboheterofunctionalization; recent developments; developments catalyzed; chemistry ... See more keywords
Regiodivergent Palladium-Catalyzed Alkene Difunctionalization Reactions for the Construction of Methylene Cyclobutanes and Methylene Cyclopentanes.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03308
Abstract: Regiodivergent palladium-catalyzed alkene difunctionalization reactions between diethyl malonate and 1,5-dienes bearing a triflate group at C2 are described. Use of tris(2,4-di-tert-butylphenyl)phosphite as a ligand leads to 4-exo-cyclization/functionalization to afford malonate-substituted methylene cyclobutanes. In contrast, the… read more here.
Keywords: regiodivergent palladium; palladium catalyzed; alkene difunctionalization; methylene cyclobutanes ... See more keywords