Recent Developments in Pd(0)-Catalyzed Alkene Carboheterofunctionalization Reactions.
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DOI: 10.1002/ajoc.201600577
Abstract: This review summarizes recent developments in palladium-catalyzed alkene carboalkoxylation and carboamination reactions. New synthetic methods that have been reported in the past four years are described, along with mechanistic issues and the influence of mechanism… read more here.
Keywords: alkene carboheterofunctionalization; recent developments; developments catalyzed; chemistry ... See more keywords
Regiodivergent Palladium-Catalyzed Alkene Difunctionalization Reactions for the Construction of Methylene Cyclobutanes and Methylene Cyclopentanes.
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DOI: 10.1021/acs.orglett.2c03308
Abstract: Regiodivergent palladium-catalyzed alkene difunctionalization reactions between diethyl malonate and 1,5-dienes bearing a triflate group at C2 are described. Use of tris(2,4-di-tert-butylphenyl)phosphite as a ligand leads to 4-exo-cyclization/functionalization to afford malonate-substituted methylene cyclobutanes. In contrast, the… read more here.
Keywords: regiodivergent palladium; palladium catalyzed; alkene difunctionalization; methylene cyclobutanes ... See more keywords
Synthesis of Biindene Derivatives via Pd-Catalyzed Alkene Difunctionalization Reactions.
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DOI: 10.1021/acs.orglett.4c01400
Abstract: The palladium-catalyzed cross-coupling of 2-allylphenyl triflate and related electrophiles with substituted indenes affords biindene derivatives in moderate to good yields with high selectivity for thermodynamically preferred alkene isomers. The transformations involve alkene nucleopalladation with indenyl… read more here.
Keywords: via catalyzed; catalyzed alkene; alkene difunctionalization; synthesis biindene ... See more keywords