Triphenylphosphine-Catalyzed Alkylative Iododecarboxylation with Lithium Iodide under Visible Light.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c03173
Abstract: Under irradiation of 456 nm blue light-emitting diodes, PPh3 catalyzes the iododecarboxylation of aliphatic carboxylic acid derived N-(acyloxy)phthalimide with lithium iodide as an iodine source. The reaction delivers primary, secondary, and bridgehead tertiary alkyl iodides… read more here.
Keywords: triphenylphosphine catalyzed; lithium iodide; catalyzed alkylative; iododecarboxylation ... See more keywords
N-Heterocyclic carbene-chromium-catalyzed alkylative cross-coupling of benzamide derivatives with aliphatic bromides.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc05026k
Abstract: Described here is a chromium-catalyzed alkylative cross-coupling of benzamide derivatives with aliphatic electrophiles under mild conditions. This reaction was promoted by a low-cost and air-stable chromium(iii) chloride salt combined with an N-heterocyclic carbene ligand and… read more here.
Keywords: chromium catalyzed; coupling benzamide; catalyzed alkylative; chromium ... See more keywords