Copper-catalyzed 1,4-alkylcyanation of CF3-containing 1,3-enynes: alkoxy radical-mediated selective cleavage of fused azabicycles.
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DOI: 10.1039/d5cc03900b
Abstract: A copper-catalyzed 1,4-alkylcyanation of CF3-containing 1,3-enynes with bicyclic hydroperoxides and TMSCN is described. In this cascade, the alkyl source originates from selective cleavage of a C-C bond in the fused bicyclic skeletons, enabling the successful… read more here.
Keywords: alkylcyanation cf3; containing enynes; catalyzed alkylcyanation; cf3 containing ... See more keywords