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Published in 2019 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201900829
Abstract: Supramolecular cavitands that contain inwardly directed functional groups have yielded specialized transformations and trapping of reactive intermediates. A recently reported 3-wall Au cavitand provides exciting opportunities for supramolecular catalysis. In this study, a variety of…
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Keywords:
acid cyclizations;
alkyne acid;
cavitand catalyzed;
chemistry ... See more keywords
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Published in 2019 at "Methods in molecular biology"
DOI: 10.1007/978-1-4939-9216-4_11
Abstract: Click chemistry has become a widely used method to insert modifications into DNA. Due to its commercial availability, 5'-ethynyl-deoxyuridine (EdU) is commonly incorporated into the DNA for subsequent modification by click reaction. However, it is…
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Keywords:
phase;
solid phase;
catalyzed alkyne;
azide cycloaddition ... See more keywords
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Published in 2019 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2018.12.011
Abstract: The synthesis and characterization of {Ln[12-MCGaIIIN(eshi)-4]}2(iph)4 and {Ln[12-MCGaIIIN(shi)-4]}2(miph)4 metallacrowns (MCs), where shi3- is salicylhydroximate, eshi3- is 4-ethynylsalicylhydroximate, iph2- is isopthalate, and miph2- is 5-maleimidoisophthalate, is reported. The ethynyl functionality allows for coupling of MCs to…
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Keywords:
using copper;
catalyzed alkyne;
azide cycloaddition;
alkyne azide ... See more keywords
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Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c04755
Abstract: A Pd-catalyzed, simple, and divergent approach for the direct synthesis of benzo[a]carbazoles from internal alkynes and N-tosyl-iodoindoles has been demonstrated. This methodology highlights the influences of reaction media and temperature for the synthesis of either…
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Keywords:
alkyne annulation;
catalyzed alkyne;
benzo carbazoles;
versatile catalyzed ... See more keywords
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Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc06214j
Abstract: The hydrosilylation of alkynes is a chief chemical method for accessing a range of alkenylsilanes, which can be derivatized to obtain value-added hydrocarbons and utilized in diverse applications. While noble metal-based catalytic procedures have shown…
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Keywords:
cobalt catalyzed;
hydrosilylation;
catalyzed alkyne;
new frontier ... See more keywords