Copper-Catalyzed Aminoarylation of Alkenes via Aminyl Radical Addition and Aryl Migration.
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DOI: 10.1021/acs.orglett.1c03973
Abstract: We describe a new strategy for aminoarylation of alkenes by copper-catalyzed smiles rearrangement using O-benzoylhydroxylamines as the amine reagent. This method affords various β-amino amide derivatives possessing a quaternary carbon center with wide functional group… read more here.
Keywords: copper catalyzed; alkenes via; catalyzed aminoarylation; aminyl radical ... See more keywords