Nickel-catalyzed aminocarbonylation of Aryl/Alkenyl/Allyl (pseudo)halides with isocyanides and H2O
Sign Up to like & getrecommendations! Published in 2020 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2020.152605
Abstract: Abstract Herein described is a nickel-catalyzed aminocarbonylation of aryl/alkenyl/allyl (pseudo)halides with isocyanides, providing aryl/alkenyl/allyl amides in 41% to 92% yields. Functional groups such as F, Cl, OMe, and heteroaromatic rings are compatible in the reaction.… read more here.
Keywords: aryl alkenyl; alkenyl allyl; nickel catalyzed; catalyzed aminocarbonylation ... See more keywords
Palladium-catalyzed aminocarbonylation of halo-substituted 7-azaindoles and other heteroarenes using chloroform as a carbon monoxide source.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc04339b
Abstract: A palladium-catalyzed aminocarbonylation of halo-substituted 7-azaindoles utilizing CHCl3 as the carbonyl source has been developed for the straightforward incorporation of an amide functional group. The protocol was extended to other heteroarenes such as pyrazolopyridines and… read more here.
Keywords: halo substituted; catalyzed aminocarbonylation; palladium catalyzed; aminocarbonylation ... See more keywords
Nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c7ra08009c
Abstract: The nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source is developed. The procedure can prepare both tertiary and secondary amides, and is applicable to various carbamoylsilanes and aryl halides containing different functional… read more here.
Keywords: catalyzed aminocarbonylation; halides using; aminocarbonylation aryl; aryl halides ... See more keywords
An Expedient Approach to Pyrazolo[3,4-b]pyridine-3-carboxamides via Palladium-Catalyzed Aminocarbonylation
Sign Up to like & getrecommendations! Published in 2021 at "Synthesis"
DOI: 10.1055/s-0037-1610783
Abstract: Pyrazolo[3,4-b]pyridine is a privileged scaffold found in many small drug molecules that possess a wide range of pharmacological properties. Efforts to further develop and exploit synthetic methodologies that permit the functionalization of this heterocyclic moiety… read more here.
Keywords: palladium catalyzed; pyridine; catalyzed aminocarbonylation; pyrazolo pyridine ... See more keywords
PALLADIUM-CATALYZED AMINOCARBONYLATION OF ARYL HALIDES.
Sign Up to like & getrecommendations! Published in 2022 at "Current organic synthesis"
DOI: 10.2174/1570179419666220430150122
Abstract: Palladium-catalyzed organic reactions are ubiquitous due to their high efficiency in coupling reaction and have wide applications in synthetic chemistry. Their widespread use in organic synthesis has been attributed to moderate conditions associated with reactions… read more here.
Keywords: catalyzed aminocarbonylation; aminocarbonylation aryl; palladium catalyzed; aryl halides ... See more keywords
Alkyl Levulinates and 2-Methyltetrahydrofuran: Possible Biomass-Based Solvents in Palladium-Catalyzed Aminocarbonylation
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28010442
Abstract: In this research, ethyl levulinate, methyl levulinate, and 2-methyltetrahydrofuran as bio-derived hemicellulose-based solvents were applied as green alternatives in palladium-catalyzed aminocarbonylation reactions. Iodobenzene and morpholine were used in optimization reactions under different conditions, such as… read more here.
Keywords: levulinates methyltetrahydrofuran; palladium catalyzed; based solvents; catalyzed aminocarbonylation ... See more keywords