Stereoselective Palladium-Catalyzed 1,3-Arylboration of Unconjugated Dienes for Expedient Synthesis of 1,3-Disubstituted Cyclohexanes
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b02747
Abstract: As significant pharmacophores, 1,3-disubstituted cyclohexanes are widespread in natural products and synthetic bioactive molecules. In this work, we describe a palladium-catalyzed arylboration of 1,4-cyclohexadienes, which allows expeditious access to an array of functionalized 1,3-disubstituted cyclohexanes… read more here.
Keywords: synthesis; arylboration; catalyzed arylboration; disubstituted cyclohexanes ... See more keywords
Synthesis of (±)-Phyltetralin by Cu/Pd-Catalyzed Arylboration
Sign Up to like & getrecommendations! Published in 2023 at "Synlett"
DOI: 10.1055/s-0041-1738434
Abstract: A synthesis of (±)-phyltetralin is reported. Notable features of the synthesis include a diastereoselective Cu/Pd-catalyzed arylboration reaction and a Matteson homologation. read more here.
Keywords: phyltetralin catalyzed; synthesis phyltetralin; catalyzed arylboration;