Ruthenium-Catalyzed Atropoenantioselective Synthesis of Axial Biaryls via Reductive Amination and Dynamic Kinetic Resolution.
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DOI: 10.1021/acs.orglett.8b02785
Abstract: The unprecedented ruthenium-catalyzed atropoenantioselective reductive amination of aldehydes with alkylamines via a cascade transfer hydrogenation and dynamic kinetic resolution strategy is described. This protocol features broad substrate scope and good functional group tolerance and allows… read more here.
Keywords: catalyzed atropoenantioselective; kinetic resolution; dynamic kinetic; reductive amination ... See more keywords