Copper(I)-catalyzed benzylic C(sp3)–H geminal difunctionalization: Successive oxidative intramolecular amidation and hydroxylation
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron"
DOI: 10.1016/j.tet.2018.11.023
Abstract: Abstract A selective copper(I)-catalyzed benzylic C(sp3)–H geminal difunctionalization reaction of a benzylic-type sp3 carbon was developed. This novel strategy allowed simultaneous introduction of amide and hydroxyl group in a highly selective and efficient way via… read more here.
Keywords: geminal difunctionalization; catalyzed benzylic; successive oxidative; sp3 geminal ... See more keywords
Mechanistic insight into aryl-nickel-catalyzed benzylic dehydrogenation of electron-deficient heteroarenes by using DFT calculations
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d1nj03119h
Abstract: We recently investigated the mechanism of aryl-nickel-catalyzed benzylic dehydrogenation of electron-deficient heteroarenes by using DFT calculations, which is an elegant protocol for accessing important precursor compounds such as 2-alkenyl heteroarenes.... read more here.
Keywords: dehydrogenation electron; catalyzed benzylic; electron deficient; benzylic dehydrogenation ... See more keywords