Pd-Catalyzed Borylsilylative Cyclization of 1,6-Allenynes.
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DOI: 10.1021/acs.orglett.2c02878
Abstract: A Pd-catalyzed borylsilylative cyclization of 1,6-allenynes with PhMe2SiBpin was developed. This method provides a practical and general method to afford the carbocycles and heterocycles bearing silyl and boryl groups with excellent regioselectivities and stereoselectivities in… read more here.
Keywords: cyclization allenynes; borylsilylative cyclization; catalyzed borylsilylative;