Regioselective O-alkylation of 2-pyridones by TfOH-catalyzed carbenoid insertion.
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DOI: 10.1039/d2cc05676c
Abstract: Selective alkylation of 2-pyridone could solve a challenge in chemistry and streamline the synthesis of important molecules. Here we report the regioselective O-alkylation of 2-pyridones by TfOH-catalyzed carbenoid insertion. In the catalytic system, alkylation of… read more here.
Keywords: catalyzed carbenoid; tfoh catalyzed; alkylation pyridones; alkylation ... See more keywords
Iron-Catalyzed Carbenoid Insertion into C(sp3)–H Bonds
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DOI: 10.1055/s-0036-1588743
Abstract: An iron-catalyzed carbenoid insertion into C–H bonds of alkanes was developed with high activity (turnover numbers up to 690 in a gram-scale experiment) and chemoselectivity. This non-heme iron-catalyzed C(sp3)–H insertion reaction provides an efficient strategy… read more here.
Keywords: insertion; iron catalyzed; catalyzed carbenoid; sp3 bonds ... See more keywords