Theoretical Investigations of Isoprene Polymerization Catalyzed by Cationic Half-Sandwich Scandium Complexes Bearing a Coordinative Side Arm
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DOI: 10.1021/acs.organomet.7b00876
Abstract: Density functional theory studies have been conducted for isoprene polymerization catalyzed by the cationic half-sandwich scandium alkyl species containing a methoxy side arm [(C5Me4C6H4OMe-o)Sc(CH2SiMe3)]+ (1) and that containing a phosphine oxide side arm [{C5Me4SiMe2CH2P(O)Ph2}Sc(CH2SiMe3)]+ (2).… read more here.
Keywords: side arm; polymerization catalyzed; isoprene polymerization; catalyzed cationic ... See more keywords