Acid-catalyzed cleavage of C-C bonds enables atropaldehyde acetals as masked C2 electrophiles for organic synthesis.
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DOI: 10.1039/d1cc04000f
Abstract: Acid-catalyzed tandem reactions of atropaldehyde acetals were established for the synthesis of three important molecules, 2,2-disubstituted indolin-3-ones, naphthofurans and stilbenes. The synthesis was realized using novel reaction cascades, which involved the same two initial steps:… read more here.
Keywords: atropaldehyde acetals; acid catalyzed; catalyzed cleavage; cleavage bonds ... See more keywords