Synthesis of 4,4-Dihydrodithienosilole and Its Unexpected Cyclodimerization Catalyzed by Ni and Pt Complexes
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00177
Abstract: 4,4-Dihydrodithienosilole (DTSH2) was isolated from a mixture of 3,3′-dibromobithiophene, n-BuLi, and H2SiCl2 and was fully characterized. The reaction of DTSH2 with a Pt(0) complex, prepared in situ from [Pt(PCy3)2] and DPPE (1,2-bis(diphenylphosphino)ethane), produced a bis(silyl)platinum… read more here.
Keywords: cyclodimerization; unexpected cyclodimerization; synthesis dihydrodithienosilole; cyclodimerization catalyzed ... See more keywords
Kinetics of Methyl Lactate Formation from the Transesterification of Polylactic Acid Catalyzed by Zn(II) Complexes
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DOI: 10.1021/acsomega.0c00291
Abstract: The kinetics of the transesterification of polylactic acid (PLA) with methanol to form methyl lactate catalyzed by Zn(II) complexes was studied experimentally and numerically. The complexes, Zn(1Et)2 and Zn(2Pr)2, were synthesized from ethylenediamine and propylenediamine… read more here.
Keywords: transesterification polylactic; polylactic acid; formation; catalyzed complexes ... See more keywords