Ruthenium-catalyzed deaminative redistribution of primary and secondary amines.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt02470c
Abstract: A ruthenium-hydride complex, [Ru(H)(Cl)(CO)(PCy3)2], was found to be active in the highly selective redistribution of primary and secondary amines bearing an α-hydrogen atom. This new deaminative coupling of amines enables the highly selective synthesis of… read more here.
Keywords: catalyzed deaminative; secondary amines; redistribution primary; primary secondary ... See more keywords
Ni-Catalyzed deaminative hydroalkylation of internal alkynes.
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DOI: 10.1039/c9cc05385a
Abstract: A regioselective cis-hydroalkylation of internal alkynes with readily prepared Katritzky pyridinium salts for the synthesis of tri-substituted alkenes is described. This reaction is the first example of a metal-catalyzed hydroalkylation of an alkyne via C-N… read more here.
Keywords: catalyzed deaminative; deaminative hydroalkylation; internal alkynes; hydroalkylation internal ... See more keywords
Ni-catalyzed deaminative cross-electrophile coupling of Katritzky salts with halides via C─N bond activation
Sign Up to like & getrecommendations! Published in 2019 at "Science Advances"
DOI: 10.1126/sciadv.aaw9516
Abstract: Reductive cross-coupling of primary amines and alkyl halides goes through a radical change. The reductive cross-coupling of sp3-hybridized carbon centers represents great synthetic values and insurmountable challenges. In this work, we report a nickel-catalyzed deaminative… read more here.
Keywords: catalyzed deaminative; cross electrophile; cross; deaminative cross ... See more keywords