Rhodium-Catalyzed β-Dehydroborylation of Silyl Enol Ethers: Access to Highly Functionalized Enolates.
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DOI: 10.1021/acs.orglett.1c03796
Abstract: An efficient rhodium-catalyzed β-dehydroborylation of aldehyde-derived silyl enol ethers (SEEs) with bis(pinacolato)diboron (B2pin2) is disclosed. The borylation reactions proceeded well with alkyl- and aryl-substituted SEEs, affording a wide array of valuable functionalized β-boryl silyl enolates… read more here.
Keywords: silyl enol; catalyzed dehydroborylation; enol ethers; rhodium catalyzed ... See more keywords