Articles with "catalyzed diamination" as a keyword



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Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to γ- or δ-Lactams.

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Published in 2018 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.7b11455

Abstract: Alkenyl N-pivaloylhydroxamates undergo an Ir(III)-catalyzed diamination of the alkene with simple exogenous secondary amines under extraordinarily mild reaction conditions. The regioselectivity of the diamination is controlled by the solvent and the electronics of the cyclopentadienyl… read more here.

Keywords: diamination; secondary amines; regiodivergent iridium; catalyzed diamination ... See more keywords