Nickel-Catalyzed 1,2-Diarylation of Simple Alkenyl Amides.
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DOI: 10.1021/jacs.8b11942
Abstract: A nickel-catalyzed conjunctive cross-coupling of simple alkenyl amides with aryl iodides and aryl boronic esters is reported. The reaction is enabled by an electron-deficient olefin (EDO) ligand, dimethyl fumarate, and delivers the desired 1,2-diarylated products… read more here.
Keywords: alkenyl amides; catalyzed diarylation; diarylation simple; simple alkenyl ... See more keywords
Copper-catalyzed diarylation of Se with aryl iodides and heterocycles
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DOI: 10.1039/c8qo00066b
Abstract: The site-selective copper-catalyzed three-component coupling reaction of electron-deficient heterocycles, Se powder and aryl iodides is disclosed. The established methodology provides an efficient and practical pathway to access 2-arylselenated heterocycles via copper-catalyzed double C–Se bond formation.… read more here.
Keywords: iodides heterocycles; catalyzed diarylation; aryl iodides; diarylation aryl ... See more keywords
Enantioselective palladium-catalyzed diarylation of unactivated alkenes.
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DOI: 10.1039/c9cc07036b
Abstract: Enantioselective Pd-catalyzed diarylation of unactivated alkenes between arenediazonium salts and arylboronic acids has been developed. This method provides an efficient route to dihydrobenzofurans with all-carbon quaternary centers in good yields with 88-99% ee. This reaction… read more here.
Keywords: catalyzed diarylation; palladium catalyzed; diarylation unactivated; unactivated alkenes ... See more keywords
Palladium-catalyzed B-Diarylation of Diethylaminoborane for the Synthesis of Diarylborinic Acids
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DOI: 10.1246/cl.200213
Abstract: The palladium-catalyzed synthesis of diarylborinic acid derivatives by intermolecular cross-coupling between aryl iodides and (amino)dihydrideborane is reported. The key to success of the reaction ... read more here.
Keywords: synthesis diarylborinic; catalyzed diarylation; diarylation diethylaminoborane; palladium catalyzed ... See more keywords