Ruthenium-catalyzed dimerization of CF3-containing functional allenes
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2021.121998
Abstract: Abstract An efficient method for the regioselective preparation of 1,3-dimethylenecyclobutanes based on Ru-catalyzed dimerization of readily available CF3-containing functionalized allenes including α-amino acid derivatives have been developed. The reactions smoothly proceed in toluene at 100… read more here.
Keywords: catalyzed dimerization; ruthenium catalyzed; cf3 containing;
Rh(i)-catalyzed dimerization of ene-vinylidenecyclopropanes for the construction of spiro[4,5]decanes and mechanistic studies
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc06986a
Abstract: Rh(i) complex catalyzed dimerization of ene-vinylidenecyclopropanes took place smoothly to construct a series of products containing spiro[4,5]decane skeletons featuring a simple operation procedure, mild reaction conditions, and good functional group tolerance. In this paper, the… read more here.
Keywords: dimerization ene; catalyzed dimerization; dimerization; ene vinylidenecyclopropanes ... See more keywords