Ionomers Modify the Selectivity of Cu-Catalyzed Electrochemical CO2 Reduction.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202201687
Abstract: Electrochemical reduction of carbon dioxide (CO 2 RR) to produce energy-rich fuels using copper (Cu)-based electrocatalysts is widely studied as a possible solution to CO 2 recycling. Ionomers are commonly used as binders to prepare… read more here.
Keywords: electrochemical co2; modify selectivity; selectivity catalyzed; ionomers modify ... See more keywords
Rh-Pd-alloy catalyzed electrochemical hydrodefluorination of 4-fluorophenol in aqueous solutions
Sign Up to like & getrecommendations! Published in 2018 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2018.03.018
Abstract: Abstract Hydrodefluorination (HDF) is the key step in fluoroaromatic pollutant (FAP) degradation, making the search for efficient HDF catalysts and the determination of the corresponding mechanism a matter of great importance. In this study, we… read more here.
Keywords: hdf; hydrodefluorination fluorophenol; catalyzed electrochemical; alloy catalyzed ... See more keywords
Complementary Copper-Catalyzed and Electrochemical Aminosulfonylation of O-Homoallyl Benzimidates and N-Alkenyl Amidines with Sodium Sulfinates.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00287
Abstract: A complementary copper-catalyzed and electrochemical aminosulfonylation of O-homoallyl benzimidates and N-alkenyl amidines with sodium sulfinates was developed. The terminal alkene substrate produced sulfone-containing 1,3-oxazines and tetrahydropyrimidines in the presence of Cu(OAc)2, Ag2CO3, and DPP, and… read more here.
Keywords: copper catalyzed; homoallyl benzimidates; homoallyl; catalyzed electrochemical ... See more keywords
Manganese-Catalyzed Electrochemical Deconstructive Chlorination of Cycloalkanols via Alkoxy Radicals
Sign Up to like & getrecommendations! Published in 2019 at "Organic Letters"
DOI: 10.1021/acs.orglett.9b03652
Abstract: A manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols has been developed. This electrochemical method provides access to alkoxy radicals from alcohols and exhibits a broad substrate scope, with various cyclopropanols and cyclobutanols converted into synthetically useful… read more here.
Keywords: alkoxy radicals; deconstructive chlorination; manganese catalyzed; catalyzed electrochemical ... See more keywords
Ruthenium-Catalyzed Electrochemical Dehydrogenative Alkyne Annulation
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b00373
Abstract: A ruthenium-catalyzed electrochemical dehydrogenative annulation reaction of aniline derivatives and alkynes has been developed for the synthesis of indoles. Electric current is used to recycle the active ruthenium-based catalyst and promote H2 evolution. The electrolysis… read more here.
Keywords: ruthenium; annulation; electrochemical dehydrogenative; catalyzed electrochemical ... See more keywords
Enantioselective Ni-Catalyzed Electrochemical Synthesis of Biaryl Atropisomers.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b13117
Abstract: A scalable enantioselective nickel-catalyzed electrochemical reductive homocoupling of aryl bromides has been developed, affording enantioenriched axially chiral biaryls in good yield under mild conditions using electricity as a reductant in an undivided cell. Common metal… read more here.
Keywords: synthesis biaryl; enantioselective catalyzed; catalyzed electrochemical; biaryl atropisomers ... See more keywords
Cu nanowire-catalyzed electrochemical reduction of CO or CO2.
Sign Up to like & getrecommendations! Published in 2019 at "Nanoscale"
DOI: 10.1039/c9nr03170g
Abstract: We prepared micrometer long Cu nanowires (NWs) of 25 and 50 nm diameters and studied their electrocatalysis for electrochemical reduction of CO/CO2 in 0.1 M KHCO3 at room temperature. The 50 nm NWs showed better… read more here.
Keywords: reduction; reduction co2; nanowire catalyzed; catalyzed electrochemical ... See more keywords
Cobalt catalyzed electrochemical [4 + 2] annulation for the synthesis of sultams
Sign Up to like & getrecommendations! Published in 2020 at "Green Chemistry"
DOI: 10.1039/d0gc00289e
Abstract: Cobalt catalyzed electrochemical [4 + 2] annulation of sulfonamides with alkynes is demonstrated in this work, which provided a practical and environmentally friendly way to synthesize structurally diverse sultams. Notably, by employing anodic oxidation in… read more here.
Keywords: electrochemical annulation; cobalt; catalyzed electrochemical; cobalt catalyzed ... See more keywords
Recent Advances in Metal-Catalyzed, Electrochemical Coupling Reactions of sp2 Halides/Boronic Acids and sp3 Centers
Sign Up to like & getrecommendations! Published in 2020 at "Synthesis"
DOI: 10.1055/s-0040-1706085
Abstract: Traditionally, metal-catalyzed cross-coupling reactions rely on stable but expensive metals, such as palladium. However, the recent development of synthetic organic electrochemistry allows for in situ redox manipulations, expanding the use of cheaper, abundant and sustainable… read more here.
Keywords: electrochemical coupling; catalyzed electrochemical; recent advances; metal catalyzed ... See more keywords
Mn(III) Catalyzed Electrochemical Reduction of CO2 on Carbon Electrodes
Sign Up to like & getrecommendations! Published in 2020 at "Croatica Chemica Acta"
DOI: 10.5562/cca3614
Abstract: Though challenging, conversion of carbon dioxide (CO2) to valuable products is an emerging area of research. Electrochemical reduction (ECR) has emerged as an efficient and rapid technique to achieve this goal. Herein, 5,10,15,20-tetraphenyl-21H, 23H-porphine manganese(III)… read more here.
Keywords: carbon; catalyzed electrochemical; iii catalyzed; co2 ... See more keywords