Iron-Catalyzed Fluoromethylene Transfer from a Sulfonium Reagent.
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DOI: 10.1021/acs.orglett.2c01757
Abstract: Herein, we report the first example of an iron porphyrin catalyzed fluoromethylene transfer from (2,4-dimethylphenyl)(fluoromethyl)(phenyl)sulfonium tetrafluoroborate to unactivated alkenes. The fluorocarbene or fluoromethylene synthon is the smallest "organic" node in a molecular graph of the… read more here.
Keywords: reagent; catalyzed fluoromethylene; fluoromethylene transfer; sulfonium ... See more keywords