Boron-Catalyzed α-Functionalizations of Carboxylic Acids.
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DOI: 10.1002/tcr.202200273
Abstract: Catalytic, chemoselective, and asymmetric α-functionalizations of carboxylic acids promise up-grading simple feedstock materials to value-added functional molecules, as well as late-stage structural diversifications of multifunctional molecules, such as drugs and their leads. In this personal… read more here.
Keywords: functionalizations carboxylic; boron catalyzed; catalyzed functionalizations; carboxylic acids ... See more keywords
Exploitation of Unconventional Electrophiles in Enantioselective Pd(0)-Catalyzed C-H Functionalizations.
Sign Up to like & getrecommendations! Published in 2019 at "Chimia"
DOI: 10.2533/chimia.2019.262
Abstract: Asymmetric metal-catalyzed C-H functionalization is a powerful strategy for the rapid generation of complex target molecules from simple precursors. While aryl (pseudo)halides have been used as electrophilic substrates in enantioselective Pd(0)-catalyzed syntheses of N-heterocycles, alternative… read more here.
Keywords: electrophiles enantioselective; unconventional electrophiles; catalyzed functionalizations; exploitation unconventional ... See more keywords