Exogenous Ligand-Free NiH-Catalyzed Hydroacylation of Aryl Alkenes with Aroyl Fluorides.
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DOI: 10.1021/acs.orglett.2c02110
Abstract: Acyl fluorides have emerged as efficient acyl group donors, but these attractive reagents have rarely been utilized in transition-metal-catalyzed hydroacylation. Herein we report a nickel hydride-catalyzed hydroacylation of aryl alkenes using aroyl fluorides. The reaction… read more here.
Keywords: hydroacylation; aroyl fluorides; hydroacylation aryl; catalyzed hydroacylation ... See more keywords
Iridium-catalyzed hydroacylation reactions of C1-substituted oxabenzonorbornadienes with salicylaldehyde: an experimental and computational study
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DOI: 10.3762/bjoc.18.30
Abstract: An experimental and theoretical investigation on the iridium-catalyzed hydroacylation of C1-substituted oxabenzonorbornadienes with salicylaldehyde is reported. Utilizing commercially available [Ir(COD)Cl]2 in the presence of 5 M KOH in dioxane at 65 °C, provided a variety… read more here.
Keywords: substituted oxabenzonorbornadienes; iridium; catalyzed hydroacylation; iridium catalyzed ... See more keywords