Palladium-Catalyzed Hydroaminocarbonylation of Alkynes with Tertiary Amines via C-N Bond Cleavage.
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DOI: 10.1021/acs.orglett.7b03331
Abstract: An efficient strategy for the cleavage of the C-N bond of tertiary amines was developed with DTBP as an oxidant, in which the cleaved H atom and amine moiety were successfully transferred to the desired… read more here.
Keywords: hydroaminocarbonylation alkynes; tertiary amines; bond; palladium catalyzed ... See more keywords