Frustrated Lewis pair catalyzed hydrodehalogenation of benzyl-halides.
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DOI: 10.1039/d1cc05943b
Abstract: 10 mol% B(2,6-C6F2H3)3 in the presence of excess tetramethylpiperidine (TMP) and H2 (or D2) is shown to catalyze the hydrogenative dehalogenation of benzyl-halides to give corresponding toluene derivatives. These reactions proceed via an initial FLP… read more here.
Keywords: lewis pair; frustrated lewis; benzyl; benzyl halides ... See more keywords