Iridium-Catalyzed Hydrosilylation of Sulfur-Containing Olefins.
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DOI: 10.1021/acs.orglett.7b02940
Abstract: Hydrosilylation of various sulfur-containing olefins with (RO)3SiH has been achieved using iridium catalysts [IrX(cod)]2 (X = Cl, SPh). The catalysis is applicable to the chemoselective hydrosilylation of thioacetate, which enables the preparation of an industrially… read more here.
Keywords: catalyzed hydrosilylation; iridium catalyzed; containing olefins; sulfur containing ... See more keywords
Cobalt-Hydride-Catalyzed Hydrosilylation of 3-Alkynes Accompanying π-Bond Migration
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DOI: 10.1021/acscatal.0c05424
Abstract: We describe a protocol for cobalt-catalyzed hydrosilylation of 3-alkynes with accompanying π-bond migration. Mechanistic studies indicate that (i) cobalt(I)-hydride bearing a bulky bisphosphine lig... read more here.
Keywords: alkynes accompanying; hydrosilylation alkynes; catalyzed hydrosilylation; bond migration ... See more keywords
Progress on Iridium-Catalyzed Hydrosilylation of Alkenes and Alkynes
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DOI: 10.1055/s-0040-1707239
Abstract: Hydrosilylation of multiple carbon–carbon bonds is a well-known process for the construction of organosilicon compounds. Nowadays, precious metal catalysts, especially platinum complexes, still occupy dominant positions in such processes. However, one important member of the… read more here.
Keywords: catalyzed hydrosilylation; iridium; hydrosilylation alkenes; iridium catalyzed ... See more keywords
Utilization of Borane-Catalyzed Hydrosilylation as a Dearomatizing Tool: Six-Membered Cyclic Amidine Synthesis from Isoquinolines and Pyridines
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DOI: 10.1055/s-0040-1707323
Abstract: In this study, a convenient strategy to synthesize six-membered cyclic amidines from isoquinolines and pyridines has been developed. Borane-catalyzed hydrosilylation of each N-heteroarene was utilized as a dearomatizing tool. Substrate scope is broad with respect… read more here.
Keywords: catalyzed hydrosilylation; six membered; isoquinolines pyridines; membered cyclic ... See more keywords