Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)
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DOI: 10.1039/c7qo00430c
Abstract: The Fe-catalyzed insertion of fluoromethylcarbenes including trifluoromethylcarbene and difluoromethylcarbene generated in situ from sulfonium salts (Ph2S+CH2CF3−OTf and Ph2S+CH2CF2H −OTf) into X–H (X = Si, C and P) bonds is described. The insertion of both carbenes… read more here.
Keywords: sulfonium salts; catalyzed insertion; insertion; fluoromethylcarbenes generated ... See more keywords